Vsepr shapes linear12/8/2023 ![]() Inversion of a generic organic amine molecule at nitrogenĪ lone pair can contribute to the existence of chirality in a molecule, when three other groups attached to an atom all differ. Fluorine is more electronegative than nitrogen and the polarity of the N-F bonds is opposite to that of the N-H bonds in ammonia, so that the dipole due to the lone pair opposes the N-F bond dipoles, resulting in a low molecular dipole moment. In contrast to NH 3, NF 3 has a much lower dipole moment of 0.234 D. There is also a dipole associated with the lone pair and this reinforces the contribution made by the polar covalent N-H bonds to ammonia's dipole moment. As the electronegativity of nitrogen (3.04) is greater than that of hydrogen (2.2) the result is that the N-H bonds are polar with a net negative charge on the nitrogen atom and a smaller net positive charge on the hydrogen atoms. Lone pairs can contribute to a molecule's dipole moment. This is an illustration of the VSEPR theory. The repulsive force of the oxygen atom's two lone pairs pushes the hydrogen atoms further apart, until the forces of all electrons on the hydrogen atom are in equilibrium. For example, in carbon dioxide (CO 2), the oxygen atoms are on opposite sides of the carbon atom ( linear molecular geometry), whereas in water (H 2O) the angle between the hydrogen atoms is 104.5° ( bent molecular geometry). This can be seen more clearly when looked at it in two more common molecules. For example, the creation of the hydronium (H 3O +) ion occurs when acids are dissolved in water and is due to the oxygen atom donating a lone pair to the hydrogen ion. They are also involved in the formation of a dative bond. ![]() The presence of a lone pair decreases the bond angle between the bonding pair of electrons, due to their high electric charge, which causes great repulsion between the electrons. The pairs often exhibit a negative polar character with their high charge density and are located closer to the atomic nucleus on average compared to the bonding pair of electrons. Angle changes Tetrahedral structure of water Yet another considers the electron localization function (ELF). The minima of the electrostatic potential V( r) is another proposed criterion. While electron density ρ( r) itself generally does not provide useful guidance in this regard, the Laplacian of the electron density is revealing, and one criterion for the location of the lone pair is where L( r) = –∇ 2ρ( r) is a local maximum. Various computational criteria for the presence of lone pairs have been proposed. The H–O–H bond angle is 104.5°, less than the 109° predicted for a tetrahedral angle, and this can be explained by a repulsive interaction between the lone pairs. In VSEPR theory the electron pairs on the oxygen atom in water form the vertices of a tetrahedron with the lone pairs on two of the four vertices. The halogens can carry three lone pairs, such as in hydrogen chloride. Two lone pairs can be found with atoms in the chalcogen group, such as oxygen in water. Lone pairs in ammonia (A), water (B), and hydrogen chloride (C)Ī single lone pair can be found with atoms in the nitrogen group, such as nitrogen in ammonia. Nevertheless, occupied non-bonding orbitals (or orbitals of mostly nonbonding character) are frequently identified as lone pairs. In molecular orbital theory (fully delocalized canonical orbitals or localized in some form), the concept of a lone pair is less distinct, as the correspondence between an orbital and components of a Lewis structure is often not straightforward. Examples are the transition metals where the non-bonding pairs do not influence molecular geometry and are said to be stereochemically inactive. However, not all non-bonding pairs of electrons are considered by chemists to be lone pairs. They are also referred to in the chemistry of Lewis acids and bases. Lone pair is a concept used in valence shell electron pair repulsion theory (VSEPR theory) which explains the shapes of molecules. Thus, the number of electrons in lone pairs plus the number of electrons in bonds equals the number of valence electrons around an atom. Electron pairs are therefore considered lone pairs if two electrons are paired but are not used in chemical bonding. They can be identified by using a Lewis structure. Lone pairs are found in the outermost electron shell of atoms. In chemistry, a lone pair refers to a pair of valence electrons that are not shared with another atom in a covalent bond and is sometimes called an unshared pair or non-bonding pair. ![]() Pair of valence electrons which are not shared with another atom in a covalent bond Lone pairs (shown as pairs of dots) in the Lewis structure of hydroxide
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Waxworks game12/8/2023 ![]() You can turn the wheel by drag & move the mouse over or press the left/right arrow keys on your keyboard or by click on arrow-buttons.Īt the top of the page, click on layer buttons to select Active code wheel layer. During combat players can target individual body parts such as head and arms. The player mainly moves around a series of tight corridors using a bitmap sprite-based point-and-click interface picking up items, solving puzzles, and engaging in combat with various horrific creatures such as zombies. Waxworks is a first-person dungeon crawl style RPG game. You should see a four-digit number (#).Įnter the number using your mouse to click the keypad on the screen. Locate the cutout window immediately above the OBJECT NAME. Just look all around the inner wheel until you find it. You have finished moving the rings around.įind the OBJECT NAME on the inner ring Don't move the ring. ![]() Rotate the inner ring so the LOCATION lines up under both the EGYPTIAN SYMBOL and MONSTER. Rotate the outer ring of the codewheel until the EGYPTIAN SYMBOL lines up with the MONSTER on the middle ring of the codewheel.įind the LOCATION on the inner ring that matches the LOCATION displayed on your screen. Find the MONSTER on the middle ring that matches the MONSTER displayed on your screen. The player moves through a series of tight corridors using a bitmap sprite-based point-and-click interface picking up items, solving puzzles, and engaging in combat with various horrific creatures, such as zombies. Take out the codewheel that was provided with your official version of the game.įind the EGYPTIAN SYMBOL on the outer ring of the codewheel that matches the EGYPTIAN SYMBOL displayed on your screen. Waxworks is a first-person, dungeon crawl-style RPG. Please follow the instructions carefully. The following instructions use the information on your screen. On your screen you will see several symbols and names that help you determine the four-digit ticket number he requires. ![]() But if you don't provide him with the right number, your relief may be short-lived. You are pleasantly surprised when he asks you for a ticket instead of attacking you. The instructions from game manual follows: When copy protection screen appears, the game show four element - Egyptian Symbol, Monster name, Location, Object name - and a numpad to type in. Game and want to purchase it, you can support the developers by doing so here.Waxworks uses 3-ply codewheel like the Horrorsoft's previous game Elvira II. This download is completely free and won't cost you a penny. Then, launch the game through the desktop shortcut. Double click inside the Waxworks folder and run the setup application.zip” (To do this you will need 7-Zip, which you can get here, or you can use the built in windows extractor). zip file and click on “Extract to Waxworks. Once the game is finished downloading, right click the.(You can use FDM which is free here, or any other download manager). We recommend using a download manager for faster download speeds. Wait 5 seconds and click on the blue ‘download now’ button.Click the Download button below and you will be redirected to UploadHaven.And a courage you’re not sure you possess.A dungeon crawler known for its gore and death scenesTravel through time and save your family from a horrible curseGreat puzzles and well-designed monsters 19th Century London, ancient Egypt, an abandoned mine shaft, a haunted cemetery and the malevolent chambers of the Waxworks itself.Your only hope to save Alex lies in removing the curse of the witch Ixona. Possessed by a 500 year old family curse, your brother schemes to resurrect the undead denizens of…Five blood-soaked worlds of the past, present and future. The terror began when you were eight and your twin brother Alex vanished into the black maze of mine tunnels beneath Vista forge – the home of your Uncle Boris’ demon-filled Waxworks.Twenty years later… Uncle Boris dies, leaving you his collection of fiendish displays – and the stupefying news that Alex is alive. Best ios contact cleaner12/8/2023 ![]() In our testing, we found it may leave behind a residue after cleaning. Reason For Avoid: However, like any product, it has its downsides. It featured with having a fast-drying formula. Reason For Like:- Improves the performance of the devices. Overall, I appreciate this fantastic product, and I found that the best electronics contact cleaner improves conductivity, Lubricates, and chemically improves electrical connections. It is a fast-acting deoxidizing solution that is widely used in such devices. It is Safe for use that not harm plastics. I also love the best electronic connector cleaner. The best thing I like about this product, the Hosa D5S-6 CAIG DeoxIT electronic cleaner spray, is chemically improved electrical connections. When deciding between Deoxit d5 vs wd40 contact cleaner, I recommend Deoxit d5 because it is a more reliable and effective choice. Also the leading supplier of analog and digital connectivity solutions for musical instruments. I want to share that Hosa Technology, Inc. is a well-known and premium brand for premium cables, adaptors, and other audio and video accessories worldwide. I like this product because it is the best spray for electrical connections available. It is one of the best, the Hosa D5S-6 CAIG DeoxIT. In addition to cleaning, protecting, and lubricating. Reason For Avoid:- Overall this is an excellent product, but some users face issues related to lubrication, and the product cost is comparatively higher. Reason For Like:- Safe and ideal for printed circuit boards, controls, battery terminals, switches, precision instruments, and electric panels. You can also check out the video tutorial on Using WD-40 Fast Drying Contact Cleaner. Here is the link to investigate and research WD-40. It is safe for all metals, electrical equipment, plastics, rubber, etc. Basically, In simple terms, the WD 40 is the BW 100 alternative.įeaturing patented Smart Straw technology, WD-40 blasts away oil, dirt, flux residue, and condensation from sensitive electronics and electrical equipment. It’s ideal for printed circuit boards, controls, switches, precision instruments, and electric panels. I love this Well-known brand in the electronics industry serving more than six decades. The best thing I noticed is that, When the formula is dried, no residue remains, but all soil is removed. That is a beautiful product, and I used it to clean solder paste stencils. ![]() I used this product when I started my career in the electronic manufacturing Industry. In the list of best electronics contact cleaners, the 2nd product is ambidextrous quality WD-40. wd-40 specialist electrical contact cleaner spray The following are my top picks for the Best Electronics Contact Cleaners. Thousands of people use them and are happy with their performance. I found that they are the best because they are fast drying, easy to use, safe for plastics, and affordable in pricing. What Are The Best Electronics Contact Cleaners?Īs per my personal experience, the best electrical contact cleaners out there on the market are the WD-40 and Hosa D5S-6 CAIG DeoxIT. I must therefore ensure that the electronic connector cleaner is safe to use when dealing with such material. Safe to use - This product can be used on most plastics, rubber, and metal on electrical equipment. Few regulations restrict high VOC or high GWP materials to solve such issues.Įvaporates Rapidly - The equipment produced with high-pressure discharge leaves no residue and disappears wholly and rapidly. ![]() So be careful while best electronics contact cleaner. That is also responsible for ozone depletion and other serious problems. So you must consider such issues when selecting the best electrical contact cleaner.Įnvironmental issues -The electronic connector cleaner is used through the spray to create a massive possibility of environmental issues. Due to that, the workers can suffer some health-related issues like headaches, dizziness, and even loss of full-body control. Toxicity - Contact cleaners to improve the cleaning performance, N-Propyl Bromide, Trichloroethylene, and Perchloroethylene are some toxic integrates. While doing all of this testing, we focused few crucial factors that I listed below We cleaned battery terminals, and wire contact surfaces and fixed some rust-related issues. We tested over 12 contact cleaners easily available on the market. I’ve probably spent 6 years of my life having contact cleaners in my hands. I have very hands-on experience dealing with various electrical spray cleaners of reputative brands. I spent more than a decade working as a repair electrician in the Boston area. FAQs – Best Contact Cleaner for Electronics.What is the Best Electrical Contact Cleaner?.Max Professional Electrical Contact Cleaner What Are The Best Electronics Contact Cleaners?. Windows 10 pro key cheap12/8/2023 Browse Microsoft Store and you'll find plenty of amazing devices that are designed to work perfectly with the latest version of Windows. When you upgrade to Windows 10, your apps will work great in all modes, on all Windows enabled devices. Specifically, you can view up to four apps and all open tasks at one time. Not only does it make multitasking easier than ever, it also interoperates well with software and hardware you already have, allowing you to stay productive whenever you need to get to work. ![]() ![]() Windows 10 delivers an even better Start Menu, expanding the possibilities and bringing over your favorite apps and pins so they're easily accessible. You'll soon discover that it is familiar to Windows users, but a more personalized experience that takes everything you already love about prior versions like Windows 7 and 8 to the next level. Get the new and improved Windows when you upgrade to Windows 10. Make use of powerful management tools for single sign on and more control over your devices. Get built-in protection from security threats at no extra cost with BitLocker, Windows Defender Antivirus and more Īccess all your files, folders and apps from virtually anywhere on any device with remote desktop Ĭhoose deferred updates so you can decide when and how to update your devices Ĭonnect to your school, business, or corporate network via the cloud with Azure Active Directory Ĭreate and run virtual machines with Hyper-V (Client Hyper-V requires a 64-bit system with second-level address translation (SLAT) capabilities and an additional 2GB of RAM.) ![]() Permanent and Authorized, 1 PC, 32/64 Bit.īuy Windows 10 Pro Professional Key Global from MMORC.COM, to get all the features of Windows 10 Home operating system plus enterprise-grade security, powerful management tools like single sign-on, and enhanced productivity with Remote Desktop and Cortana: Note: You must REINSTALL system, CAN'T upgrade from Windows 10 Home to Pro, and cant upgrade from Windows 7 to Windows 10 Pro too. Does instagram dm compress images12/8/2023 Repair damaged photos with all levels of corruption, such as grainy photos, dark photos, pixelated photos, faded photos, etc. The powerful tool to repair photos is excellent yet very easy to use. Those who already are, are in heaven because they can repair the photo within minutes, and those who have never heard about it, fastened their seat belts because the roller coaster of Wondershare Repairit - Photo Repair is about to start. Not everyone is aware of this magical tool. So, to help you regarding how to fix blurry photos on Instagram few guiding methods are attached in the coming section Method 1: Wondershare Repairit - Photo Repair Tool What people think when they see a blurry photo is how to fix blurry Instagram photos on Android but sadly, they don't have the answer because if they did, then the problem would have been resolved. People sometimes get annoyed by the bad photo quality and that the image looks blurry, and this is a very common complaint seen among all Instagram users. The full of the fun platform is getting in trouble as photo results are affected by few factors, as discussed. ![]() Uploading photos from other devices will definitely harm and reduce the photo quality because the application is predominantly mobile-based. Instagram is a mobile-based application, yet people also use it on other devices such as desktops, laptops, etc. Hence, during the conversion, the file loses its quality. In case the user is uploading an image file in any format other than this format, then Instagram will covert the format to. ![]() The default file format accepted by Instagram is JPEG (.jpg) extension. This way, the photo will be of the standard size that is acceptable to upload, but it damages the picture quality, and it looks blurry. If you are uploading an image with an incorrect aspect ratio, then Instagram will compress and crop the photo. If the file size is over 1MB, then Instagram will compress it. It does not trouble the uploading process, but it does affect the photo quality, and the image looks blurry. When uploading a photo on Instagram, the file size matters a lot. But have you ever pondered on the reason why this happens? If not, then let's discuss few reasons why photos look blurry The photos generally get blurry after upload. They can chat, face time friends, and even do live sessions.Ī common complaint from different Instagram users is that the photo quality changes when you upload a photo. The fun-oriented platform allows users to upload amazing content on their accounts. The most commonly used social media platform that aids in providing information, entertainment, and interesting insiders about the life of different celebrities. Snow accumulation massachusetts12/8/2023 County officials estimated that the power would be back on for 99 percent of Cape residents by 11:59 p.m. ![]() Thousands of residents on Cape Cod were still waiting for their power to come back on late Sunday afternoon as cleanup from Saturday’s powerful nor’easter got underway.Īn estimated 38,000 homes across the Cape still hadn’t had their power restored as of Sunday afternoon, according to the Barnstable County Regional Emergency Planning Committee. Thousands of Cape Cod homes without power - 4:46 p.m. “You just have to be patient and do the best you can.” “We’ll get through it, we always do,” she said. “It was very, very cold, but also very picturesque and beautiful.”įrancis has lived in Chatham for four years and previously spent 30 years in Vermont, so she’s no stranger to intense winter weather. and the sun was out and the sky was blue,” she said. Monday.įrancis said she stepped outside on Sunday and it was rather nice with the sun shining despite the bitter cold. “Anyone who was anticipating staying here night called us 24 to 48 hours prior and made the decision not to make the journey.”Įversource said it was expecting to have power back on for virtually all Chatham residents by 6 p.m. “We were closed but I do have a few locals staying here tonight who don’t have heat in their homes,” she said. No guests stayed at the Inn on Saturday, all having canceled their visits, Francis said, but a few area residents, including a woman in her 90s, were spending the night there on Sunday after losing power and heat in their homes. ![]() ![]() Sunday, including at the Chatham Inn, where general manager Lyn Francis said the Inn’s generator was keeping the lights and heat on in the lobby and a few of rooms. Customers still without power in Chatham - 6:53 p.m.Ībout 86 percent of customers in Chatham were still without power as of 6 p.m. Avid mediacentral editorial12/8/2023 ![]() For security, the ability to export cuts, or export to file can also be added or removed for specific users. ![]() ![]() Different options and features can be toggled on/off, including function settings in the bins, tracks, outputs, project formats, project creation, framerates, and other tools within Media Composer. The site administrator can go into the specific settings for a user or a group, and select specific functions that can be performed. Media Composer | Enterprise allows an administrator to customize the Media Composer interface based on roles and functions at your post house or media facility. Customizing Media Composer Layouts For Users We will go over these in more detail below.Īlright, let’s get into the Avid Media Composer | Enterprise products and how it will help your post production become more efficient. Enterprise consists of three products- MediaCentral | Editorial Management, Avid MediaCentral | Cloud UX, and Media Composer: Distributed Processing. Not to mention Phrasefind, Scriptsync, and Pro Tools integration- but we can save that for another blog.Īvid Media Composer | Enterprise takes what Media Composer is good at and adds a new level of functionality for Facility Engineers, Director of Production Operations, and creative collaborators alike. Media Composer has continued to be the standard for broadcast and productions that require a higher level of collaboration- large volumes of media, file deliverables, and teams working from anywhere. What Is Avid Media Composer | Enterprise?Īvid Media Composer has been the backbone editing software platform of choice for motion pictures, television, documentary post production and film schools for years. Anylist recipe import12/7/2023 ![]() You should now have the file path /opt/recipes/mediafiles/recipes/openeats-import/upload/. After that you'll need to copy the /code/site-media/upload folder from the openeats API docker container to the openeats folder you created. ![]() To import your images you'll need to create the folder openeats-import in your Tandoor's recipes media folder (which is usually found inside /opt/recipes/mediafiles). json file and simply import it using the importer. manage.py dumpdata recipe ingredient rating recipe_groups > recipe_ingredients.json ![]() This command might also work docker exec -it openeats_api_1. If you followed the default installation method you can use the following command docker-compose -f docker-prod.yml run -rm -entrypoint 'sh' api. You need to run the command python manage.py dumpdata recipe ingredient inside of the application api container. Luckily it is relatively easy to export it from the command line. OpenEats does not provide any way to export the data using the interface. This zip file can simply be imported into Tandoor. Recipe keeper allows you to export a zip file containing recipes and images using its apps. The generated file can simply be imported into Tandoor.Īs I only had limited sample data feel free to open an issue if your RezKonv export cannot be imported. To migrate from RezKonv Suite to Tandoor select Export > Gesamtes Kochbuch exportieren (the last option in the export menu). The RezKonv format is primarily used in the german recipe manager RezKonv Suite. If you have MealMaster recipes that cannot be imported feel free to raise an issue. Second line notes to ingredients are currently also not imported as a note but simply put into the instructions. Currently, only the one column format for ingredients is supported. The MealMaster spec allows for many variations. Meal master can be imported by uploading one or more meal master files. Or is worse than this feel free to provide me with more example data and I can try to improve the importer.Īs ChefTap cannot import these files anyway there won't be an exporter implemented in Tandoor. Usually the import should recognize all ingredients and put everything else into the instructions. Images are also not supported as they are not included in the export (at least This makes importing it very hardĪnd leads to suboptimal results. This format is basically completely unstructured and every export looks different. The export is a zip file containing a folder calledĬheftap_export which in turn contains. Images are not included in the export andĬhefTaps allows you to export your recipes from the app (I think). Simply export the recipes from Pepperplate and upload the zip to Tandoor. The import of all data without losing anything. These files are well-structured and allow zip file containing all of your recipes as. paprikarecipes file is basically just a zip with gzipped contents. PaprikaĪ Paprika export contains a folder with a html representation of your recipes and a. Safron exports do not contain any images. Simply upload the file and choose the Nextcloud Cookbook type. Click on the three dot Actions and press Download.Select the recipes you want to export or use the checkbox at the top of the list to select all of them.Open the Recipes folder where your recipes are stored.Structured information most of your recipe is going to be intact.įollow these steps to import your recipes Importing recipes from Nextcloud cookbook is very easy and since Nextcloud Cookbook provides nice, standardized and Go to Import/Export and select Export Recipes. Images are currently not supported for exporting. Selected and import the json file in RecipeSage. To migrate from Tandoor to RecipeSage simply export with Recipe Sage The RecipeSage integration also allows exporting. Go to Settings > Export Recipe Data and select EXPORT AS JSON-LD (BEST). It is also one of the few recipe formats that is actually structured in a way that allows forĮasy machine readability if you want to use the data for any other purpose. It is maintained with new fields added and contains all data to transfer your recipes from one installation to another. The default integration is the built in (and preferred) way to import and export recipes. ✔️ = implemented, ❌ = not implemented and not possible/planned, ⌚ = not yet implemented Default Overview of the capabilities of the different integrations. That said for most of the people getting this application running with their recipes is the biggest priority.īecause of this importing as many formats as possible is prioritized over exporting.Įxporter for the different formats will follow over time. 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None of the many decorative stitches came out as they were supposed to. With every decorative stitch I dialed up, I encountered a problem. This is by far the biggest time waster I’ve encountered on any new sewing machine. Then you would have to go through the same process with the button on the right. In order to get back to your straight stitch after completing the decorative stitch, you must press the button on the left through the entire numerical sequence from 4 through 9 before getting back to 0. If you want a decorative stitch in the 30-40 range… let’s say stitch number 35, you must first press the up arrow on the left from 0 to 3, then the one on the right until you get to 5. The basic straight stitch assignment is 00. When sewing a combination of stitches or switching from straight to decorative stitches and back, you must press these buttons far more than I believe is necessary. If you go past the stitch you want by accident, you have to go through the whole cycle again to get back to the stitch you want. First of all, if you want to use a certain stitch, you have to press the arrow up buttons to get to the stitch you want. The real problem arose when I tried to use the decorative stitch options. I wasn’t, however, thrilled with the fact that the ‘variable’ needle position was pre-set, giving the user absolutely no control over when and where to position the needle for custom sewing tasks. When I sampled different stitch lengths and widths, the Singer Brilliance 6180 performed well. The straight and zigzag stitches were not the greatest I’ve seen, but they were well defined and tight. ![]() I then re-checked the bobbin to make sure it was wound and inserted properly. I took out the upper thread and threaded it myself. When I got to her house, the machine was threaded properly and everything seemed to be fine. Stitch guide helps new users determine when and how to use built-in utility stitches.80 built-in decorative and utility stitches. ![]() FeaturesĪccording to the owner’s manual, the Singer Brilliance 6180 has the following on-board features: I did, however, notice that the Brilliance does not offer a start/stop button, variable speed control, drop feed, or the capacity for the user to control the variable needle positioning. In addition, the bright LED light above the needle shed provided illumination for the work surface. The thread guides were clearly defined on the top and front of the machine and were very easy to follow. The stitch design panel is clearly displayed on the front right panel, with the LCD situated directly above the stitch selection and length/width adjustment buttons. In all honesty, the Singer Brilliance 6180 doesn’t look much different from any of the other new Singer models, so I fully expected it to function much the same as well. When I arrived, she had the machine all set up with the accessories, instruction manuals, and instructional DVD on a nearby table. AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |